• 专利附录
  • 专利说明
  • 权利要求
  • 类似技术
  • 同族专利
  • 引用文献
  • 法律状态
  • 优先权
    • 专利摘要:
    Broad parts are formed on at least one passage including a passage for forming the thinnest layer among passages for respective resin layers of a multilayer sheet at an upstream side of a confluence. In the broad parts, clearances become larger to both ends of the passage along the width thereof.
    公开号:US20010005517A1
    申请号:US09/767,725
    申请日:2001-01-24
    公开日:2001-06-28
    发明作者:Tadahiro Kegasawa；Kazuo Ozaki；Shotaro Ogawa；Ryuichi Katsumoto；Hideaki Usui
    申请人:Tadahiro Kegasawa；Kazuo Ozaki；Shotaro Ogawa；Ryuichi Katsumoto；Hideaki Usui；
    IPC主号:B29C48-313
    专利说明:
    [0001] 1. Field of the Invention [0001]
    [0002] The present invention relates generally to a method and apparatus for forming multilayer sheets, and more particularly to a method for forming multilayer sheets for photographic printing paper supports wherein each thickness of individual layers composing the sheet is uniform widthwise and a extrusion die therefor. [0002]
    [0003] 2. Description of Related Art [0003]
    [0004] A coextrusion apparatus is usually used for forming multilayer sheets or films for photographic printing paper supports. A feed block die cannot make each of resin layers composing a multilayer sheet have uniform thickness widthwise, in particular if there are great differences in viscosity, temperature and flow rate between melted resins, which form the resin layers. Even if a multi-manifold die, which forms relatively small unevenness of thickness of each layer, is used, it is difficult to obtain multilayer sheets with an extremely small unevenness of thickness of each layer that is desired for the multilayer sheets for the photographic printing paper supports. [0004]
    [0005] To solve these problems, several techniques have been suggested for adjusting the thickness of each layer by means of a multi-manifold die. For example, Japanese Utility Model Provisional Publication No. 54-107664 discloses a multi-manifold die that adjusts they clearances in the entire passages extending from manifolds to a confluence, where the melted resins join one another through the respective passages, with use of a choke bar mechanism. Japanese Patent Provisional Publication No. 52-60853 discloses a method for manufacturing a coextrusion film. According to this method, at least one choke bar facing the confluence adjusts a confluent angle formed by the passages of the melted resins at the confluence. Japanese Utility Model Provisional Publication No. 7-15321 discloses a multilayer sheet forming apparatus providing a passage sectional area adjusting means, which forms a thin plate and pushes and pulls the thin plate along the thickness of the thin plate at the non-passage side of the thin plate, at a part in at least one of plural passages from the manifolds to the confluence. According to Japanese Patent Publication No. 60-37781, manifolds are straight, and there is provided a passage that becomes wider from the center of the die towards both ends thereof, and a slot that becomes narrower from the center of the die towards both ends thereof. [0005]
    [0006] The-above-mentioned techniques, however, have a problem in that it is extremely difficult to eliminate the unevenness of thickness of each of resin layers composing the multilayer sheet along the width thereof or to obtain the multilayer sheet that has a small unevenness of thickness of each layer. [0006]
    [0007] In particular, the above-mentioned arts are disadvantageous to form the multilayer sheets for the photographic printing paper supports, wherein there are great differences in viscosity, temperature and flow rate between the melted resins, which form the resin layers, and it is required that the unevenness of thickness of each layer along the width thereof is ±1 μm or less. [0007] SUMMARY OF THE INVENTION
    [0008] The present invention has been developed under the above-described circumstances, and has as its object the provision of a method for forming a multilayer sheet and an extrusion apparatus therefor that is able to form a multilayer sheet composed of resin layers on the condition that melted resins forming the layers are greatly different from one another in viscosity, temperature and flow rate, and unevenness of thickness of each layer along the width thereof is required to be extremely small. [0008]
    [0009] To achieve the above-mentioned object, the present invention is directed to a method for forming a multilayer sheet by means of a multilayer sheet forming apparatus in which a plurality of melted resins join at a confluence through respective passages, the melted resins are piled in layers at the confluence, and the melted resins are extruded through a slot to form the multilayer sheet, broad parts being formed on upstream side of the confluence of at least one passage including a passage for forming the thinnest layer among the passages, the broad parts having clearances which become larger toward both ends of the passage along the width thereof. [0009]
    [0010] Furthermore, to achieve the above-mentioned object, the present invention is directed to a multilayer sheet forming apparatus which forms a multilayer sheet by extruding melted resins from a slot, wherein: the melted resins are supplied to a plurality of manifolds, the supplied resins are extended at the manifolds along widths of passages connecting the manifolds to a confluence, the extended resins are piled in layers at the confluence, and the piled resins are extruded from the slot; a pair of broad parts are formed on at least one of the passages at an upstream side of the confluence, the at least one of the passages including the passage for forming the thinnest layer among the layers, the pair of broad parts having clearances that become larger from broadening start points to both ends of the at least one of the passages along the width thereof; a relation between a total width (W) of the pair of broad parts and a width (L) of the at least one of the passages is W≧0.1 L; and a relation between a clearance (de) of the broad part at the end of the at least one of the passages and a clearance (dc) at the broadening start point is 2.0≧de/dc>1.0. [0010]
    [0011] According to the present invention, the broad parts are formed on at least one passage including the passage for forming the thinnest layer among the passages for respective resin layers of the multilayer sheet at the upstream side of the confluence. In the broad parts, the clearance becomes larger toward both ends of the passage along the width thereof. Consequently, the thickness of the resin layers including the thinnest layer is uniform along the width thereof. [0011] BRIEF DESCRIPTION OF THE DRAWINGS
    [0012] The nature of this invention, as well as other objects and advantages thereof, will be explained in the following with reference to the accompanying drawings, in which like reference characters designate the same or similar parts throughout the figures and wherein: [0012]
    [0013] FIG. 1 is a view illustrating the appearance of a multilayer coextrusion apparatus according to the present invention; [0013]
    [0014] FIG. 2 is a sectional view taken along line [0014] 2-2 of FIG. 1;
    [0015] FIG. 3 is an enlarged view of a part A in FIG. 2; [0015]
    [0016] FIG. 4 is a view of assistance in explaining the widths of broad parts and clearances at the broad parts in a passage of the extrusion die according to the present invention; [0016]
    [0017] FIG. 5 is a view of assistance in explaining a clearance in a passage of a conventional extrusion die; [0017]
    [0018] FIG. 6 is a sectional view of assistance in explaining a restriction bar that forms the broad parts; [0018]
    [0019] FIG. 7 is a conceptional section view taken along the width of the multilayer sheet formed in an embodiment 1; [0019]
    [0020] FIG. 8 is a conceptional section view taken along the width of the multilayer sheet formed in a comparative example 1; and [0020]
    [0021] FIG. 9 is a conceptional section view taken along the width of the multilayer sheet formed in a comparative example 2. [0021] DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENT
    [0022] This invention will be described in further detail by way of example with reference to the accompanying drawings. [0022]
    [0023] FIG. 1 shows the appearance of a coextrusion apparatus including a multilayer sheet or film forming die [0023] 10 according to the present invention. FIG. 2 is a sectional view taken along a line 2-2 of FIG. 1.
    [0024] As shown in FIGS. 1 and 2, the extrusion die [0024] 10 comprises manifolds 18, 20 & 22 to which respective melted resins are supplied through supply passages 12, 14 & 16 from screw extruders (not shown), a confluence 24 where the melted resins are piled in layers, passages 26, 28 & 30 that connect the manifolds 18, 20 & 22 to the confluence 24, a slot 32 through which the multiple layers of resins are extruded from the confluence 24 to the outside, and a regulation bolt 34 that regulates a clearance of the slot 32. A plurality of die blocks 37 are combined to construct the manifolds 18, 20 & 22, the passages 26, 28 & 30, and the slot 32 in the extrusion die 10.
    [0025] When the coextrusion apparatus forms a multilayer sheet [0025] 36 for a photographic printing paper support, the melted resins, which are different in viscosity, are supplied to the manifolds 18, 20 & 22, and they are extended along the width of the passages 26, 28 & 30 at the manifolds 18, 20 & 22 so as to form sheet or film-like streams. Then, the melted resins join at the confluence 24 through the passages 26, 28 & 30. The melted resins are piled in layers at the confluence 24, and they are extruded from the slot 32 onto a printing paper substrate 39, which moves on a cooling roller 38. The substrate 39 is covered with the extruded resin layers between the cooling roller 38 and a nip roller 41, and becomes the multilayer sheet 36 for the photographic printing paper base. The multilayer sheet 36 separates from the cooling roller 38 via a release roller 42.
    [0026] As shown in FIG. 3, broad parts [0026] 26A, 28A & 30A are formed on a upstream side of the confluence 24 of at least one passage including the passage that forms the thinnest layer among the passages 26, 28 & 30 for the respective layers of the multilayer sheet 36.
    [0027] FIG. 4 shows positions and clearances of the broad parts [0027] 30A formed in the passage 30, for example. As shown in FIG. 4, the broad parts 30A are formed at both ends of the passage 30. The clearances are larger at the broad parts than at the central part of the passage. The clearances become larger from broadening start points toward the ends of the passage 30 or the ends of the broad part 30A. The broad parts 30A from the broadening start points to the ends of the passage 30 may be straight as shown in FIG. 4 or may be curved inward or outward. Whether the broad parts are straight or curved depends on rheological characteristics, temperature, flow rate, etc. of the melted resins.
    [0028] The width of the broad parts [0028] 30A formed at both ends of the passage 30 and the amount of clearances at the broad parts 30A satisfy conditions stated below.
    [0029] The total width W of the broad parts [0029] 30A formed at both ends of the passage 30 must satisfy the following inequality (1):
    [0030] where W[0030] 1 is the width of the broad part of one side, W2 is the width of the broad part of the other side; and L is the width of the passage 30. The total width W is preferably equal to or larger than 0.12 L, and more suitably equal to or larger than 0.15 L.
    [0031] The clearance of the passage at the broad parts [0031] 30A must satisfy the following inequality (2):
    [0032] where dc is the clearance at the broadening start point, and de is the clearance at the end of the passage de/dc is preferably between 1.0 and 1.8, more suitably between 1.2 and 1.6. [0032]
    [0033] FIG. 5 shows a passage in a conventional extrusion die, and the clearance is uniform at both ends and central part of the passage. [0033]
    [0034] To form the broad parts [0034] 30A of the passage 30, the die blocks 37 of the extrusion die 10 are machined in such a way as to satisfy the above-mentioned conditions (1) and (2), or a restriction bar 40 that forms desired broad parts may be fixed in a hole (not shown) in the die blocks 37 to form the passage 30 with the broad parts 30A as shown in FIG. 6. It is convenient to use the restriction bar 40 since a plurality of restriction bars 40, which are different in width and clearance of the broad parts 30A, can be exchanged in accordance with the Theological characteristics, temperature, flow rate, etc. of the melted resin.
    [0035] A description will be given of the operation of the above-described extrusion die for the multilayer sheet by way of an example in which the broad parts [0035] 26A, 28A & 30A are formed at the passages 26, 28 & 30, respectively, by means of the restriction bars 40. In this example, the multilayer sheet 36 is composed of three layers: a bottom layer 36A, an middle layer 36B, and a top layer 36C. The thinnest layer of these three layers is the top layer 36C (see FIGS. 7-9 ).
    [0036] The restriction bars [0036] 40, which are provided at the passages 26, 28 & 30, form the broad parts 26A, 28A & 30A suitable for the viscosity, temperature and flow rate of melted resins flowing through the passages 26, 28 & 30. It is necessary to know a relationship between the conditions such as the viscosity, temperature and flow rate of the flowing resins and the various restriction bars 40 in advance by test runs.
    [0037] The melted resins supplied to the manifolds [0037] 18, 20 & 22 join at the confluence 24 through the passages 26, 28 & 30, respectively. The melted resins are piled in layers at the confluence 24, and they are extruded onto the printing paper substrate 39 through the slot 32. In the conventional apparatus, when the multilayer melted resins are extruded, the balance of extrusion pressure along the width of the passages 26, 28 & 30, which form the layers 36A, 36B & 36C, can be lost due to the differences in viscosity, temperature and flow rate between the melted resins, which become the layers 36A, 36B & 36C of the multilayer sheet 36. In particular, when the viscosity and flow rate of the thinnest layer 36C are smaller than those of the other layers 36A, 36B, the pressure for extruding the melted resin flowing through the passage 30 for example is smaller at the ends of the passage than at the central part. Accordingly, the melted resin tends to flow intensively at the central part of the passage 30 for the thinnest layer 36A, and thus, the multilayer sheet 36 has the thinnest layer 36C with the thick central part and thin both ends (see FIG. 8). To eliminate this disadvantage, the extrusion die 10 according to the present invention is provided with broad parts at both ends of the passage in areas where the extrusion pressure is small. The broad parts are formed in such a way as to satisfy the inequality (1).
    [0038] There is a difference in pressure at both ends of the passage, where the extrusion pressure is small. As the position is near the end of the passage, the extrusion pressure downs. For this reason, it is necessary to satisfy the inequality (2) in order to adjust the clearance at the broad part in accordance with the difference in extrusion pressure. [0038]
    [0039] As stated above, according to the present invention, at least one of the broad parts [0039] 26A, 28A & 30A are formed on the upstream side of the confluence 24 for at least one passage including the passage that forms the thinnest layer 36C among the passages 26, 28 & 30 for the layers 36A, 36B & 36C, respectively. This makes the layers 36A, 36B & 36C of the multilayer sheet 36, particularly the thinnest layer 36C a uniform thickness along the width of the multilayer sheet 36. EXAMPLE
    [0040] A description will now be given of an example wherein the above-described coextrusion apparatus forms the multilayer sheet [0040] 36 composed of the top layer 36C, the middle layer 36B and the bottom layer 36A.
    [0041] TABLE 1 shows the conditions of the formation of the multilayer sheet [0041] 36. TABLE 1 Extrusion temperature [° C.] 300 (all the layers) Width of passage [mm] 1000 Line speed (speed of substrate) 150 [m/min] Substrate material Paper of 180 g/m2 Resin Top layer Low density polyethylene (MI = 10) Middle layer Low density polyethylene (MI = 3) (added with pigment) Bottom layer Low density polyethylene (MI = 5) Flow rate [kg/hr] Top layer  15 Middle layer 185 Bottom layer 100 Extruder Top layer φ2.5 inch single spindle extruder Middle layer φ3.5 inch single spindle extruder Bottom layer φ3.5 inch single spindle extruder
    [0042] TABLE 2 shows the clearances of the passages [0042] 26, 28 & 30 on the upstream sides of the confluence 24. TABLE 2 Clearance of bottom layer passage 1.5 mm flat (no broad part) Clearance of middle layer passage 2.5 mm flat (no broad part) Clearance of top layer passage Clearance at central part: 0.5 mm Embodiment 1 Width of broad part: 360 mm (W1 = W2 = 180 mm) Clearance at broad part: passage end 0.75 mm, Broadening start point 0.5 mm Clearance of top layer passage 0.5 mm flat (no broad part) Comparative example 1 Clearance of top layer passage Clearance at central part: 0.5 mm Comparative example 2 Width of broad part: 360 mm (W1 = W2 = 180 mm) Clearance at broad part: passage end 1.25 mm, Broadening start point 0.5 mm
    [0043] In the embodiment 1 according to the present invention, broad parts are formed at both ends of the top layer passage. The total width of the broad parts is 360 mm (180 mm+180 mm) so that the ratio of the broad part width (W) to the passage width (L) can be 0.36 to satisfy the condition W≧0.1 L (the inequality [0043] 1). The clearance at the ends of the passage is 0.75 mm, and the clearance at the broadening start points is 0.5 mm. Consequently, de/dc is 1.5, which satisfies the condition 2.0≧de/dc>1.0 (the inequality 2). The clearance at the center of the passage is 0.5 mm.
    [0044] In the comparative example 1, the clearance of the passage is constant at 0.5 mm, which is the same as the clearance at the center of the passage in the embodiment 1. [0044]
    [0045] In the comparative example 2, broad parts are formed at both ends of the top layer passage as is the case with the embodiment 1. The clearance at the passage ends is 1.25 mm, and the clearance at the broadening start points is 0.5 mm. Consequently, de/dc is 2.5, which exceeds the range 2.0≧de/dc>1.0 (the inequality [0045] 2).
    [0046] In the embodiment 1 and the comparative examples 1 and 2, no broad part is formed in the passages [0046] 26 & 28 for the bottom layer 36A and the middle layer 36B, so that the clearances are constant.
    [0047] TABLE 3 shows the evaluation results obtained by measuring the unevenness in thickness of the layers [0047] 36A, 36B & 36C along the width thereof. FIG. 7 is a conceptional section view obtained by observing the section of the multilayer sheet in the embodiment 1 through a microscope. Likewise, FIG. 8 is a conceptional section view of the multilayer sheet in the comparative example 1, and FIG. 9 is a conceptional section view of the multilayer sheet in the comparative example 2. TABLE 3 Embodi- Comparative Comparative ment 1 example 1 example 2 Thickness of top layer [μm]  1.5 ± 0.3  1.5 ± 2.0  1.5 ± 1.5 Thickness of middle layer [μm] 18.5 ± 0.8 18.5 ± 2.5 18.5 ± 2.0 Thickness of bottom layer [μm] 10.0 ± 0.5 10.0 ± 0.5 10.0 ± 0.5
    [0048] As is clear from TABLE 3, the unevenness of the thickness of the top layer [0048] 36C (the thinnest layer) in the embodiment 1, in which the broad parts are formed so as to satisfy the above-mentioned conditions (1) and (2), is ±0.3 μm, which is much smaller than ±1 μm that is the maximum permissible unevenness of thickness of the layer of the multilayer sheet for the photographic printing paper base whose unevenness is required to be extremely small. As shown in FIG. 7, the top, middle and bottom layers of the obtained multilayer sheet-are uniform in thickness widthwise.
    [0049] To the contrary, the unevenness of the top layer in the comparative example 1, where the broad parts are not formed, is ±2.0 μm, which is much larger than that of the embodiment 1. As shown in FIG. 8, if the broad parts are not provided in the passage forming the top layer [0049] 36C, the top layer 36C is formed only at the central part of the passage, not at both ends of the passage. If the broad parts are not provided in the passage forming the thinnest layer as mentioned above, the extrusion pressure is smaller at the ends of the passage than at the central part thereof, and the melted resin flows intensively to the central part of the passage.
    [0050] In the comparative example 2 in which the clearances at the broad parts exceed the range of the above inequality (2), the unevenness of the top layer [0050] 36C is ±1.5 μm, which is smaller than the unevenness in the comparative example 1 but is larger than the unevenness in the embodiment 1. As shown in FIG. 9, in the comparative example 2, the top layer 36C is thinner at the central part than at both ends. In other words, even if the broad parts are provided in the passage, the resin layer cannot be uniform in thickness along the width thereof if de/dc exceeds 2.0.
    [0051] When de/dc is less than 1.0, the formed top layer is not uniform in thickness along the width thereof. [0051]
    [0052] As set forth hereinabove, according to the method for forming the multilayer sheet and the coextrusion apparatus therefor of the present invention, the simple structure in which the broad parts are provided makes the thickness of each layer of the multilayer sheet uniform along the width thereof, even if there are great differences in viscosity, temperature and flow rate between the resins forming the layers of the sheet. In particular, by providing the broad parts in the passage forming the thinnest resin layer, the unevenness of the thickness of each layer of the multilayer sheet for the photographic printing paper base can be extremely small. By providing the broad parts, the die does not become large in size. [0052]
    [0053] Accordingly, the present invention makes it possible for the compact extrusion die to stably manufacture the multilayer sheet of which resin layers are uniform in thickness along the width thereof. Consequently, the use of the extrusion die according to the present invention makes it possible to manufacture the multilayer sheet for the photographic printing paper base, which is excellent in flatness with little distortion and unevenness. [0053]
    [0054] Furthermore, since the extrusion die is compact, the air gap can be small during the extrusion to thereby reduce the neck-in of the extruded resin layer. It is therefore possible to reduce the waste selvages (both ends of the multilayer sheet). [0054]
    [0055] It should be understood, however, that there is no intention to limit the invention to the specific forms disclosed, but on the contrary, the invention is to cover all modifications, alternate constructions and equivalents falling within the spirit and scope of the invention as expressed in the appended claims. [0055]
    权利要求:
    Claims (4)
    [1" id="US-20010005517-A1-CLM-00001] 1. A method for forming a multilayer sheet by means of a multilayer sheet forming apparatus in which a plurality of melted resins join at a confluence through respective passages, the melted resins are piled in layers at the confluence, and the melted resins are extruded through a slot to form the multilayer sheet, broad parts being formed on upstream side of said confluence of at least one passage including a passage for forming the thinnest layer among said passages, said broad parts having clearances which become larger toward both ends of said passage along the width thereof.
    [2" id="US-20010005517-A1-CLM-00002] 2. A multilayer sheet forming apparatus which forms a multilayer sheet by extruding melted resins from a slot, wherein:
    the melted resins are supplied to a plurality of manifolds, the supplied resins are extended at the manifolds along widths of passages connecting the manifolds to a confluence, the extended resins are piled in layers at the confluence, and the piled resins are extruded from the slot;
    a pair of broad parts are formed on at least one of the passages at an upstream side of the confluence, said at least one of the passages including the passage for forming the thinnest layer among the layers, the pair of broad parts having clearances that become larger from broadening start points to both ends of said at least one of the passages along the width thereof;
    a relation between a total width (W) of the pair of broad parts and a width (L) of said at least one of the passages is W≧0.1 L; and
    a relation between a clearance (de) of the broad part at the end of said at least one of the passages and a clearance (dc) at the broadening start point is 2.0≧2 de/dc>1.0.
    [3" id="US-20010005517-A1-CLM-00003] 3. The multilayer sheet forming apparatus of
    claim 2 , wherein the broad parts are formed by machining die blocks forming the confluence.
    [4" id="US-20010005517-A1-CLM-00004] 4. The multilayer sheet forming apparatus of
    claim 2 , wherein the broad parts are formed by fitting a restriction bar into a hole formed in die blocks forming the confluence, the restriction bar being used for forming a desired broadening.
    类似技术:
    公开号 | 公开日 | 专利标题
    US4695236A|1987-09-22|Apparatus for continuous extrusion of a multilayer synthetic resin web
    US7090479B2|2006-08-15|Apparatus and method for manufacturing resin molded product
    US6203742B1|2001-03-20|Method for forming multilayer sheets and extrusion die therefor
    US3559239A|1971-02-02|Multilayer extrusion die
    EP0161812B1|1989-07-05|Multimanifold extrusion die and coextrusion process
    US3797987A|1974-03-19|Coextrusion apparatus for flat film
    EP1426164B1|2012-07-04|Method forming resin film
    CA1230718A|1987-12-29|Valve plate and feedblock design for co-extrusionapparatus and co-extrusion process using same
    EP0353064B1|1997-01-15|Method and apparatus for feeding a plurality of molten resin jet streams into T die
    EP0574733B1|1997-09-17|End feed extrusion
    EP0781641B1|2001-11-07|Method for forming multilayer sheet or multilayer film
    EP0084450B2|1991-05-02|Thermoplastic film extruding t-die
    EP0834388B1|2002-04-10|Adjustable coextrusion feedblock
    JPH06122142A|1994-05-06|Co-extrusion flat die
    US20100213632A1|2010-08-26|Method and apparatus for manufacturing molded plate
    JP2597007B2|1997-04-02|Extrusion composite adapter
    JP2004142339A|2004-05-20|T die and method of extrusion molding of thermoplastic resin laminated product
    JPH06344414A|1994-12-20|Co-extrusion multi-layer molding method
    JPH0715321U|1995-03-14|Composite sheet manufacturing equipment
    JP2668843B2|1997-10-27|Feed block for forming multi-layer composite film or sheet
    JP3626770B2|2005-03-09|Composite adapter for extrusion
    JPH0761672B2|1995-07-05|Composite adapter for extrusion
    JPH09193228A|1997-07-29|Method for molding plural layer sheet or plural layer film
    JP2882987B2|1999-04-19|Multi-layer film extrusion equipment
    JPH0716991B2|1995-03-01|Composite adapter for extrusion
    同族专利:
    公开号 | 公开日
    JP3931391B2|2007-06-13|
    NL1009929C2|2001-12-19|
    JPH1158493A|1999-03-02|
    US6203742B1|2001-03-20|
    NL1009929A1|1999-02-23|
    US6461138B2|2002-10-08|
    引用文献:
    公开号 | 申请日 | 公开日 | 申请人 | 专利标题
    JPS5260853A|1975-11-13|1977-05-19|Mitsui Polychemicals Ltd|Method of producing coaxial extrusion film|
    JPS54107664A|1978-02-10|1979-08-23|Mitsubishi Electric Corp|Programmable counter|
    JPS6037781B2|1980-03-28|1985-08-28|Mitsubishi Heavy Ind Ltd||
    JPS6243846B2|1980-05-20|1987-09-17|Fuji Photo Film Co Ltd||
    JPS6037781A|1983-08-10|1985-02-27|Matsushita Electric Ind Co Ltd|Driving method for fet|
    DE3405257C2|1984-02-15|1986-05-22|Reifenhäuser GmbH & Co Maschinenfabrik, 5210 Troisdorf|Device for the continuous extrusion of a multilayer plastic web|
    US4533308A|1984-04-16|1985-08-06|Peter Cloeren|Multimanifold extrusion die and coextrusion process|
    US4600550A|1984-04-27|1986-07-15|Cloeren Peter|Coextrusion process for overcoming the curtaining effect|
    JPS6243846A|1985-08-21|1987-02-25|Tdk Corp|Optical recording disk|
    JPS62149411A|1985-12-24|1987-07-03|Shin Kobe Electric Mach Co Ltd|Manufacture of co-extruded sheet|
    US4789513A|1987-06-05|1988-12-06|P.C.E. Corp.|Coextrusion apparatus and process|
    US5211898A|1988-07-27|1993-05-18|Tomy Machinery Manufacturing Co., Ltd.|Method and apparatus for feeding a plurality of molten resin jet streams into T die|
    US5045264A|1990-03-29|1991-09-03|Dowbrands, Inc.|Method and apparatus for making extruded plastic film with strips embedded therein of a second thermoplastic material|
    DE4140146A1|1990-12-21|1992-06-25|Greiner & Soehne C A|Extruder for scrap or impure material - passes melt through special aperture which only allows coarse particles to flow in core of melt so that surface of prod. has good finish|
    US5147195A|1991-06-13|1992-09-15|The Cloeren Company|Extrusion apparatus with adjustable flow-restricting member|
    DE4302438A1|1993-01-29|1994-08-04|Blaupunkt Werke Gmbh|Circuit arrangement for frequency division by an odd number|
    EP0781641B1|1995-12-28|2001-11-07|Fuji Photo Film Co., Ltd.|Method for forming multilayer sheet or multilayer film|
    JP3931391B2|1997-08-22|2007-06-13|富士フイルム株式会社|Multilayer support molding method and molding die apparatus thereof|JP3931391B2|1997-08-22|2007-06-13|富士フイルム株式会社|Multilayer support molding method and molding die apparatus thereof|
    US6837698B2|2001-12-19|2005-01-04|3M Innovative Properties Company|Multilayer coextrusion die and method|
    US6949283B2|2001-12-19|2005-09-27|3M Innovative Properties Company|Polymeric coextruded multilayer articles|
    JP3944846B2|2002-12-03|2007-07-18|富士フイルム株式会社|Method and apparatus for forming resin film|
    US7150616B2|2003-12-22|2006-12-19|Kimberly-Clark Worldwide, Inc|Die for producing meltblown multicomponent fibers and meltblown nonwoven fabrics|
    KR20070121780A|2005-03-22|2007-12-27|도시바 기카이 가부시키가이샤|Die for molding multi-layer film sheet|
    KR101244996B1|2005-12-26|2013-03-18|코니카 미놀타 어드밴스드 레이어즈 인코포레이티드|Process for producing cellulose film, apparatus for producing cellulose film, optical film produced by said production apparatus, polarizing plate using said optical film, and liquid crystal display device|
    WO2011140019A1|2010-05-07|2011-11-10|3M Innovative Properties Company|Apparatus for manufacturing multilayer polymeric films|
    JP5898858B2|2011-05-31|2016-04-06|エスカーボシート株式会社|Laminate gradation method|
    US10926446B1|2018-12-11|2021-02-23|Facebook Technologies, Llc|Methods and systems for fabricating layered electroactive materials|
    法律状态:
    2006-03-17| FPAY| Fee payment|Year of fee payment: 4 |
    2007-02-15| AS| Assignment|Owner name: FUJIFILM CORPORATION, JAPAN Free format text: ASSIGNMENT OF ASSIGNORS INTEREST;ASSIGNOR:FUJIFILM HOLDINGS CORPORATION (FORMERLY FUJI PHOTO FILM CO., LTD.);REEL/FRAME:018904/0001 Effective date: 20070130 Owner name: FUJIFILM CORPORATION,JAPAN Free format text: ASSIGNMENT OF ASSIGNORS INTEREST;ASSIGNOR:FUJIFILM HOLDINGS CORPORATION (FORMERLY FUJI PHOTO FILM CO., LTD.);REEL/FRAME:018904/0001 Effective date: 20070130 |
    2010-03-31| FPAY| Fee payment|Year of fee payment: 8 |
    2014-05-16| REMI| Maintenance fee reminder mailed|
    2014-10-08| LAPS| Lapse for failure to pay maintenance fees|
    2014-11-03| STCH| Information on status: patent discontinuation|Free format text: PATENT EXPIRED DUE TO NONPAYMENT OF MAINTENANCE FEES UNDER 37 CFR 1.362 |
    2014-11-25| FP| Expired due to failure to pay maintenance fee|Effective date: 20141008 |
    优先权:
    申请号 | 申请日 | 专利标题
    JP22620897A|JP3931391B2|1997-08-22|1997-08-22|Multilayer support molding method and molding die apparatus thereof|
    JP9-226208||1997-08-22||
    US09/137,833|US6203742B1|1997-08-22|1998-08-21|Method for forming multilayer sheets and extrusion die therefor|
    US09/767,725|US6461138B2|1997-08-22|2001-01-24|Device for forming multilayer sheets and extrusion die therefor|US09/767,725| US6461138B2|1997-08-22|2001-01-24|Device for forming multilayer sheets and extrusion die therefor|
    [返回顶部]